What is the trend for atomic radius?

1 min readjanuary 10, 2021

AP Chemistry 🧪

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Periodic Trends: The Atomic Radius

There are two things you should know about the periodic trend for atomic radius:

First, atomic radius increases as you go down the periodic table.

  • The higher the period, the higher the energy level. Energy levels are represented by the coefficients when you write electron configurations (ex. the 1 in 1s², the 2 in 2p⁶, etc.).
  • Electrons in the highest energy level are farthest away from the nucleus, so the size of the electron cloud increases going down the periods.

Second, atomic radius decreases from left to right across a period.

  • This is because the effective nuclear charge increases with the addition of more protons.
  • Effective nuclear charge is the net positive charge felt by valence electrons, estimated by (number of protons) - (inner electrons). In carbon, for example, the effective nuclear charge is +4 (6 protons minus 2 electrons in the first shell). 
  • In short, because you're adding protons, electrons feel a stronger attraction to the nucleus and the size of the atom decreases.
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    Source: ThoughtCo

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